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5. Cruella De Vil (Glenn Close), 101 Dalmatians
The crazy, dramatic unkempt locks. The stark black-and-white motif. Are you thinking what we're thinking? Puppy killer! Fashion designer Cruella De Vil is the pinnacle of chic (and evil), and she's got the hair prove it. Give her all the hair spray she wants, but just don't let her near your canines. She's bringing up the rear of the top five for this totally out-there look.
101 Dalmatians, 1996. Photo courtesy of the Everett Collection.











